cis-Bis(2,2′-bipyrimidine-κ2 N 1,N 1′)dibromidomanganese(II) nitromethane monosolvate
نویسنده
چکیده
The asymmetric unit of the title compound, [MnBr(2)(C(8)H(6)N(4))(2)]·CH(3)NO(2), contains one half of a neutral Mn(II) complex and one half of a nitro-methane solvent mol-ecule, the complete mol-ecules being generated by the application of twofold symmetry. In the complex, the Mn(II) ion has a distorted cis-Br(2)N(4) octa-hedral coordination geometry defined by four N atoms of the two chelating 2,2'-bipyrimidine ligands and two Br(-) ions. There are intra- and inter-molecular C-H⋯Br and C-H⋯N contacts.
منابع مشابه
cis-Diaquabis(2,2′-bipyrimidine-κ2 N 1,N 1′)manganese(II) bis(perchlorate) nitromethane disolvate monohydrate
The asymmetric unit of the title compound, [Mn(C(8)H(6)N(4))(2)(H(2)O)(2)](ClO(4))(2)·2CH(3)NO(2)·H(2)O, contains one half of a cationic Mn(II) complex, a ClO(4) (-) anion, a nitro-methane solvent mol-ecule and one half-mol-ecule of water. The complex mol-ecule and the solvent water mol-ecule are located on a twofold rotation axis. In the complex, the Mn(II) ion has a distorted cis-N(4)O(2) oct...
متن کاملcis-(Acetonitrile-κN)aquabis(2,2′-bipyrimidine-κ2 N 1,N 1′)manganese(II) cis-diaquabis(2,2′-bipyrimidine-κ2 N 1,N 1′)manganese(II) tetrakis(perchlorate) dihydrate
The asymmetric unit of the title compound, [Mn(CH(3)CN)(C(8)H(6)N(4))(2)(H(2)O)][Mn(C(8)H(6)N(4))(2)(H(2)O)(2)](ClO(4))(4)·2H(2)O, contains two distinct cationic Mn(II) complexes, four perchlorate anions and two solvent water mol-ecules. In the two complexes, both Mn(II) ions are six-coordinated in a distorted octa-hedral environment, but one Mn ion has a cis-N(5)O coordination geometry defined...
متن کاملcatena-Poly[[[dibromidomanganese(II)]-μ-2,2′-bipyrimidine-κ4 N 1,N 1′:N 3,N 3′]dihydrate]
The asymmetric unit of the title compound, {[MnBr(2)(C(8)H(6)N(4))]·2H(2)O}(n), contains one half of a repeat unit of the neutral linear coordination polymer and a solvent water mol-ecule, with the Mn(II) ion on a crystallographic twofold axis. In the polymer, inversion-related Mn(II) ions are bridged by the bis-chelating 2,2'-bipyrimidine (bpym) ligands, thereby forming a chain structure along...
متن کاملBis(2,2′-bipyrimidine-κ2 N 1,N 1′)palladium(II) bis(tetrafluoroborate) acetonitrile monosolvate
The reaction of [Pd(MeCN)(4)](BF(4))(2) with 2,2'-bipyrimidine (bpm) in MeCN-CHCl(3) afforded the title compound, [Pd(C(8)H(6)N(4))(2)](BF(4))(2)·C(2)H(3)N. The asymmetric unit contains two half complexes, with the Pd(II) atoms both lying on a twofold axis. Each metal atom adopts a tetra-hedrally distorted square-planar geometry. In the crystal, [Pd(bpm)(2)] dications are linked by C-H⋯N hydrog...
متن کاملcis-Bis(2,2′-bipyrimidine-κ2 N 1,N 1′)diiodidomanganese(II)
The asymmetric unit of the title complex, [MnI(2)(C(8)H(6)N(4))(2)], contains one half of a neutral Mn(II) complex, with the entire molecule completed by the application of twofold symmetry. The Mn(II) ion is six-coordinated in a distorted octa-hedral environment defined by four N atoms of the two chelating 2,2'-bipyrimidine (bpym) ligands and two I(-) anions in a cis-N(4)I(2) coordination geom...
متن کامل